Methods for thermal transfer with a semiconductor

ABSTRACT

Thermal transfer between a semiconductor wafer and a platen during vacuum processing is provided through a soft, thermally-conductive polymer layer having a thin, hard surface film. The soft polymer layer, which is preferably silicone rubber containing thermally-conductive particles, conforms to surface irregularities on the wafer and has low thermal resistance. The surface film is preferably silicon dioxide in the form of a multiplicity of flat plates integrally formed on the silicone rubber. Adherence of the wafer and of foreign matter to the polymer layer is prevented by the surface film. In addition, the underlying polymer layer is protected by the surface film. A high purity polymer layer is fabricated by evacuating the mold cavity and the resin container prior to injection of resin. The mold for the polymer layer utilizes a hard, smooth mold release surface and a resilient gasket between the platen and the mold release surface. The gasket establishes the dimensions of the polymer layer and seals the mold cavity. The surface film is formed by oxygen plasma treatment of the silcone rubber layer.

CROSS REFERENCE TO RELATED APPLICATION

This application is a continuation of application Ser. No. 07,331,698, filed 3-31-89 abandoned which is a continuation in part of application Ser. No. 141,709, filed Jan. 7, 1988 now U.S. Pat. No. 4,832,781.

FIELD OF THE INVENTION

This invention relates to processing of semiconductor wafers in a vacuum chamber and, more particularly, to methods and apparatus for transferring thermal energy to or from a semiconductor wafer in vacuum utilizing a soft, thermally-conductive silicone rubber layer having a smooth, nonstick surface film comprising a plurality of plates.

BACKGROUND OF THE INVENTION

In the fabrication of integrated circuits, a number of well-established processes involve the application of ion beams to semiconductor wafers in vacuum. These processes include ion implantation, ion beam milling and reactive ion etching. In each instance, a beam of ions is generated in a source and is directed with varying degrees of acceleration toward a target wafer. Ion implantation has become a standard technique for introducing impurities into semiconductor wafers.

The energetic ions in an ion beam applied to a semiconductor wafer generate heat in the wafer This heat can become significant, depending on the energy level and current level of the ion beam and can result in uncontrolled diffusion of impurities beyond prescribed limits in the wafer. A more severe problem with heating is the degradation of patterned photoresist layers which are often applied to semiconductor wafers before processing and which have relatively low melting points.

Other semiconductor wafer processes such as ion etching, sputter deposition and etching, ion beam deposition, vacuum evaporation, plasma etching and chemical vapor deposition are performed in vacuum and may result in undesired heating of the wafer. In some instances, the process may require heat to be transferred to the wafer.

In commercial semiconductor processing, a major objective is to achieve a high throughput in terms of wafers processed per unit time. One way to achieve high throughput is by automation of the process for increased speed, reduced human handling of wafers, and more uniform and particulate-free devices. Another way to achieve high throughput in the case of an ion beam system is to use a relatively high current beam so that the desired process is completed in a shorter time. However, large amounts of heat are likely to be generated in the wafers being processed. Thus, it is necessary to provide wafer cooling in order to prevent the above-described detrimental effects of elevated temperatures.

A serious difficulty in effecting thermal transfer in vacuum is that thermal energy is blocked from conduction through a vacuum. The rate of thermal transfer from a semiconductor wafer by radiation is inadequate for most processes. Therefore, to achieve adequate rates of thermal transfer by conduction, it is necessary to physically contact the wafer with a thermally-conductive medium coupled to a heat sink. Although such a system is straightforward in principle, efficient wafer cooling for automated ion implantation systems has been difficult to achieve for a number of reasons.

Since the front of the wafer must be exposed for ion beam treatment, any clamping must be at the periphery or by centrifugal force. Direct solid-to-solid contact between a wafer and a flat metal heat sink is relatively ineffective since any bowing or irregularities in the back surface of the wafer result in regions where the wafer does not contact the heat sink surface. Furthermore, where contact does occur, microscopic voids in the wafer and heat sink surfaces result in actual physical contact occurring over only about five percent of the two surfaces. As a result, thermal transfer is poor. A contoured heat sink surface for optimizing conductive heat transfer between a wafer and a heat sink is disclosed in U.S. Pat. No. 4,535,835, issued Aug. 20, 1985 to Holden. The heat sink surface is contoured so as to impose a load that results in a uniform contact pressure distribution and a stress approaching the elastic limit of the wafer for a peripherally clamped wafer.

Other techniques for limiting wafer temperature during processing have included batch processing in which the incident ion beam is time-shared over a number of wafers so that the heating on any particular wafer is limited. A thermally-conductive fluid can be confined by a flexible diaphragm which contacts the back of the wafer as disclosed in U.S. Pat. Nos. 4,580,619 issued Apr. 8, 1986 to Aitken and 4,682,566 issued July 28, 1987 to Aitken.

The technique of gas conduction has also been utilized for wafer cooling in vacuum. Gas is introduced into a cavity behind a semiconductor wafer and effects thermal coupling between the wafer and a heat sink. Gas-assisted solid-to-solid thermal transfer with a semiconductor wafer is disclosed in U.S. Pat. No. 4,457,359 issued July 3, 1984 to Holden. A semiconductor wafer is clamped at its periphery onto a shaped platen. Gas under pressure is introduced into the microscopic void region between the platen and the wafer. The gas pressure approaches that of the preloading clamping pressure without any appreciable increase in the wafer-to-platen spacing, thereby reducing the thermal resistance. When gas conduction cooling is utilized, it is necessary to confine the gas to the region behind the wafer and to prevent escape of the gas into the vacuum chamber, since gas escaping into the vacuum chamber is likely to have detrimental effects on the process being performed.

Another prior art technique for thermal transfer in vacuum involves the use of a thermally-conductive polymer between a semiconductor wafer and a heat sink. A tacky, inert polymer film for providing thermal contact between a wafer and a heat sink is disclosed in U.S. Pat. No. 4,139,051 issued Feb. 13, 1979 to Jones et al. The polymer film disclosed by Jones et al has a sticky surface which is used to advantage to retain the wafer in position during processing. However, such a sticky surface is unacceptable in automated processing, wherein the wafer must easily be removed after ion beam treatment. The use of sticky surfaces in automated equipment often results in wafer breakage during wafer removal, or in an inability to remove the wafer from the sticky surface at all. Furthermore, particles, dust and other undesired materials tend to adhere to the sticky polymer surface and to contaminate subsequent wafers. In addition, cleaning of foreign matter from the sticky surface is difficult.

An automated wafer clamping mechanism utilizing a pliable thermally-conductive layer between a semiconductor wafer and a heat sink is disclosed in U.S. Pat. No. 4,282,924 issued Aug. 11, 1981 to Faretra. The wafer is clamped at its periphery to a convexly-curved platen having a layer of thermally-conductive silicone rubber on its surface. The Faretra apparatus has provided satisfactory thermal transfer under a variety of conditions. However, sticking of wafers to the silicone rubber surface has occasionally been a problem. To limit such sticking, relatively hard silicone rubbers have been utilized. However, the relatively hard silicone rubber is less effective with respect to thermal transfer, and intimate contact between the wafer and the convexly curved silicone rubber surface is not always achieved.

A technique for modifying the surface of a polymeric material utilizing ion implantation of selected ions is disclosed in British Patent Application No. 2,071,673A, published Sept. 23, 1981. However, the British publication contains no disclosure of a technique for preventing stickiness on polymer surfaces.

Imperfections and gas bubbles in the silicone rubber or other polymer layer can seriously degrade thermal transfer performance. When a gas bubble that is present during the molding process leaves a void on the surface of the silicone rubber layer, thermal transfer is reduced in the area of the void. When gas bubbles are located within the bulk of the silicone rubber layer, they can gradually outgas during vacuum processing, thereby causing a virtual leak in the vacuum chamber. It has been difficult to achieve a silicone rubber layer that is uniform and free of gas bubbles.

While the curved platens disclosed in U.S. Pat. Nos. 4,535,835 and 4,282,924 increase the area of contact between the wafer and the thermally-conductive surface, they introduce a spatial variation in angle between the incident ion beam and the wafer surface. In some processes such as ion implantation, angle-of-incidence variations can be a serious problem. The depth of penetration of incident ions is a function of incident angle because of the well-known channeling effect. Therefore, it is desirable in ion implantation to provide a constant angle-of-incidence between the ion beam and the wafer surface over the surface area of the semiconductor wafer.

It is a general object of the present invention to provide improved apparatus for effecting thermal transfer with a workpiece in vacuum.

It is another object of the present invention to provide a thermally-conductive polymer layer for effecting highly efficient thermal transfer between a semiconductor wafer and a heat sink or a heat source.

It is a further object of the present invention to provide a thermally-conductive polymer layer having a nonstick surface for thermal transfer with a semiconductor wafer.

It is still another object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer wherein the wafer is maintained substantially flat during processing.

It is still another object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer, including a thermally-conductive polymer layer having a thin surface film which substantially prevents adherence of the wafer.

It is a further object of the present invention to provide apparatus for effectively cooling a semiconductor wafer during processing in vacuum so as to permit a relatively high level of incident energy.

It is a further object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer, which is simple in construction and low in cost.

It is another object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer, including a thermally-conductive polymer layer having an extremely smooth surface for enhanced thermal transfer.

It is still another object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer, including a thermally-conductive polymer layer that is very soft so as to conform to surface irregularities of the semiconductor wafer.

It is another object of the present invention to provide an improved method for effecting thermal transfer with a workpiece in vacuum.

It is another object of the present invention to provide a method of treating a thermally-conductive polymer layer used for thermal transfer with a semiconductor wafer to prevent adherence of the wafer to the polymer layer.

It is yet another object of the present invention to provide apparatus for thermal transfer with a semiconductor wafer including a thermally-conductive polymer layer having a thin surface film comprising a plurality of plates.

SUMMARY OF THE INVENTION

According to the present invention, these and other objects and advantages are achieved in apparatus for effecting thermal transfer with a workpiece, such as a semiconductor wafer, in vacuum comprising a thermally-conductive platen including a heat transfer surface, a first thermally-conductive layer affixed to the heat transfer surface for conforming to the shape of a surface of the workpiece, and a second thermally-conductive layer that is thin relative to the first layer, affixed to the first layer and having a smooth surface for contacting the workpiece without adhering thereto.

The first layer is typically a thermally-conductive polymer layer, and is preferably silicone rubber having thermally-conductive particles dispersed therein and having a hardness characterized by a durometer value less than about 20 Shore A. The second layer is preferably an oxide surface film formed by oxygen plasma treatment of the silicone rubber layer.

The first and second layers conform to irregularities on the back surface of the semiconductor wafer and provide excellent contact between the wafer and the second layer. The second layer is extremely smooth so as to provide uniform contact over the area of the semiconductor wafer and has little or no tendency to adhere to the wafer thereby facilitating automated wafer processing and handling. Preferably, the second layer is fractured into a plurality of plate-like members which individually conform to the back surface of the wafer and further enhance intimate contact therebetween.

According to another aspect of the present invention, there is provided a method for effecting thermal transfer with a workpiece, such as a semiconductor wafer. The method comprises the steps of providing a thermally-conductive platen having a heat transfer surface, affixing a soft, thermally-conductive polymer layer to the heat transfer surface, forming on the polymer layer a thin surface film for contacting the workpiece without adhering thereto, and pressing the workpiece into contact with the surface film. Preferably, the step of forming the surface film includes the step of oxygen plasma treatment of the polymer layer sufficient to form an oxide surface film having a thickness in the range of 0.1 to 5.0 micrometers.

According to yet another aspect of the invention, there is provided a method for treating a thermally-conductive polymer layer used for thermal transfer with a semiconductor wafer to prevent adherence of the wafer to the polymer layer. The method comprises the step of forming a thin surface film on the polymer layer, the surface film being harder than the polymer layer. Preferably, the polymer layer comprises silicone rubber having thermally-conductive particles dispersed therein, and the step of forming a surface film includes the step of oxygen plasma treatment of the silicone rubber to form an oxide surface film.

According to still another aspect of the invention, there is provided a method for treating a thermally-conductive polymer layer used for thermal transfer with a workpiece to prevent adherence of the workpiece to a surface of the polymer layer. The method includes the steps of treating the polymer layer with oxygen plasma, and providing silicon from an independent source of silicon at the surface of the polymer layer during oxygen plasma treatment to cause formation of a thin surface film on the polymer layer. The surface film is harder than the polymer layer. The silicon can be provided from any convenient source such as a volatile liquid, a gas or a heated solid. The polymer layer can be heated prior to oxygen plasma treatment in order to drive volatile materials from the polymer layer.

BRIEF DESCRIPTION OF THE DRAWINGS

For a better understanding of the present invention together with other and further objects, advantages and capabilities thereof, reference is made to the accompanying drawings which are incorporated herein by reference and in which:

FIG. 1A is a schematic block diagram of a vacuum processing system utilizing thermal transfer apparatus in accordance with the present invention;

FIG. 1B is a block diagram illustrating a rotating disk for centrifugal clamping of wafers during ion implantation;

FIG. 2 is an enlarged, partial cross-sectional view of a semiconductor wafer and the thermal transfer apparatus of FIG. 1A;

FIG. 3 is an enlarged, partial cross-sectional view of a polymer layer and a wafer in accordance with the prior art;

FIG. 4 is an enlarged, partial cross-sectional view of a polymer layer and a semiconductor wafer in accordance with the present invention;

FIG. 5A is a block diagram of molding apparatus in accordance with the present invention shown during evacuation of the apparatus;

FIG. 5B is a block diagram of molding apparatus in accordance with the present invention shown during an injection of polymer resin into the mold cavities;

FIG. 6 is a cross sectional view of a mold for fabricating a polymer layer;

FIG. 7 is a block diagram illustrating the polymer layer fabrication process; and

FIG. 8 is a block diagram of apparatus suitable for formation of a thin surface film on a thermally conductive polymer layer.

DETAILED DESCRIPTION OF THE INVENTION

A block diagram of a vacuum processing system utilizing thermal transfer apparatus is shown in FIG. 1A. A semiconductor wafer 10 is mounted on thermal transfer apparatus 12. The wafer 10 and the thermal transfer apparatus 12 are positioned in a chamber 14 that is evacuated to a specified pressure range by a vacuum pumping system 16. An ion beam source 18 directs an ion beam 20 at the wafer 10 for implantation of impurity dopants, etching, or some other desired function and causes undesired heating thereof. The system illustrated in FIG. 1A can represent an ion implantation system, a reactive ion etch system or any other processing system which utilizes an ion beam for treating the semiconductor wafer 10.

When the system is an ion implantation system, the ion beam 20 from source 18 is mass analyzed and focused to produce a well-defined beam of a desired ion species. Relative movement of the ion beam 20 and the wafer 10 by electrostatic or magnetic deflection of beam 20, by mechanical movement of wafer 10, or by a combination thereof produces a uniform ion dose distribution over the wafer surface. Most ion implantation systems fall into two general categories: (1) serial systems which utilize electrostatic beam deflection and which process one or two wafers at a time; and (2) batch systems in which up to 25 wafers are mounted on a rotating disk and the beam is scanned over the rotating disk by magnetic deflection of the beam or by mechanical translation of the rotating disk. In either type of system, the thermal energy imparted to the wafers by the ion beam 20 can be significant and must be removed by a carefully designed wafer cooling system.

In automated systems, the wafer or wafers are positioned in a target chamber which can be isolated from the main beamline to facilitate rapid vacuum pumping. An end station including an automatic wafer transfer system introduces semiconductor wafers into target positions in the target chamber, aligns the wafers with respect to a target plane, provides cooling of the wafers during implantation and removes the wafers from the target chamber after inplantation is complete. At each target position, means must be provided for retaining the wafer in position during implantation and for cooling the wafer. A serial system has one or two target positions, while a batch system has multiple target positions.

The thermal transfer apparatus 12 at each target position includes a thermally-conductive layer 30 affixed to a heat transfer surface 32 of a platen 34. While the layer 30 can be any suitable thermally-conductive material, it is typically a polymer layer. The polymer layer 30 is formed of a resilient material, such as an elastomer, that conforms to surface irregularities on the wafer 10 and then returns to its original shape after the wafer 10 is removed. Although the polymer layer 30 can be formed separately, it typically is molded in place on heat transfer surface 32. The polymer layer 30 is soft to enhance thermal transfer and has a thin, platelike surface layer or film 50 that is harder than polymer layer 30 to prevent adherence to the wafer 10, as described in detail hereinafter. The semiconductor wafer 10 is pressed into intimate contact with a front surface 38 of surface film 50 by a force 40 that is preferably maximized. For centrifugal clamping as described below, the force 40 is typically about 0.02 lbs/cm². Thermal energy imparted to the wafer 10 by ion beam 20 is transferred by conduction through surface film 50 and polymer layer 30 to platen 34 and is removed by appropriate cooling means.

Preferably, the force 40 that presses wafer 10 into contact with surface film 50 is a centrifugal force resulting from rotation of the thermal transfer apparatus 12 about a prescribed axis. As shown in FIG. 1B, the thermal transfer apparatus 12 is mounted on a disk 42 that is rotated by a motor 44. Wafer mounting sites 46 are positioned around the periphery of disk 42, and thermal transfer apparatus 12 is provided at each site 46. Each wafer site 46, including thermal transfer apparatus 12, is tilted relative to an axis of rotation 48 so as to provide a centrifugal force tending to press wafer 10 into contact with surface film 50. The apparatus of FIG. 1A has the advantage that the entire wafer surface is exposed for treatment by ion beam 20, and no wafer area is lost because of peripheral clamping rings. In addition, the wafer is flat so that the angle of incidence of ion beam 20 is constant over the wafer surface.

Alternatively, peripheral clamping of wafer 10 can be utilized, as known in the prior art. When peripheral clamping is utilized, it is usually desirable to provide a contoured surface as described in U.S. Pat. Nos. 4,282,924 and 4,457,359 to insure contact between the wafer and the surface film 50 over the surface area of the wafer.

The platen 34 is typically aluminum or another thermally conductive material and is preferably liquid cooled to increase the rate of thermal transfer. Liquid cooling may be provided by coolant passages (not shown) in the body of platen 34, by tubes (not shown) mounted on the back surface of platen 34 for the circulation of a liquid coolant, or by any other conventional cooling means.

An enlarged partial cross-sectional view of the thermal transfer apparatus 12 is shown in FIG. 2. The back surface 36 of polymer layer 30 becomes adhered to heat transfer surface 32 of platen 34 during the molding process described hereinafter. The polymer layer 30 is very soft in order that both surface film 50 and polymer layer 30 may conform to irregularities on the back surface of wafer 10 and to any undesired foreign matter between wafer 10 and surface film 50. In one preferred embodiment, the polymer layer 30 is a silicone rubber containing thermally-conductive particles 52 which can be aluminum oxide, graphite or carbon, or any other suitable thermally-conductive material. The thermally-conductive particles preferably have a cross-sectional dimension on the order of 40 micrometers or less. As noted above, the silicone rubber is extremely soft and preferably has a hardness of durometer value 20 Shore A or less.

Prior art thermally conductive silicone rubber layers were typically fabricated with a hardness of durometer value in the range of 50 to 70 Shore A to limit wafer sticking, or adherence, to the silicone rubber layer, since it was known that soft silicone rubber layers were stickier than hard ones. In accordance with the present invention, the problem of sticky silicone rubber surfaces is overcome by providing thin surface film 50, which is hard relative to underlying polymer layer 30, on the front surface of polymer layer 30. The surface film 50 is an extremely smooth surface that does not adhere to the back of wafer 10 and that provides very uniform and intimate contact with the back of wafer 10. In a preferred embodiment, the surface film 50 is an oxide formed by oxygen plasma treatment of the silicone rubber as described hereinafter. The oxide film has a probable composition of SiO₂, or quartz, which is contiguous with the bulk of the silicone rubber layer. The surface film 50 may be a single contiguous film, but usually takes the form of a multiplicity of flat plates, for example plates 50a, 50b, 50c, 50d, having dimensions varying from about 5 to 1,000 micrometers across, depending on the mechanical stress or thermal stress applied to the surface film 50 during or after fabrication of the thermal transfer apparatus. Each flat plate 50a, 50b, 50c, 50d has a smooth top surface. In this embodiment, the surface film 50 has a selected thickness in the range of 0.1 to 5 micrometers, while the polymer layer 30 has a selected thickness in the range of 0.001 inch to 0.020 inch. Preferably, the surface film 50 is a factor of at least 10 harder than polymer layer 30, and polymer layer 30 is at least 50 times thicker than surface film 50.

The surface film 50 contacts the back side of the wafer 10 and conforms to the wafer because each of the plates 50a, 50b, 50c, etc. is free to float on the soft, flexible polymer layer 30 below it. The hard surface film 50 is resistant to mechanical abrasion and damage because of the inherent hardness and strength of quartz. Adherence to the wafer is also eliminated because the quartz surface separates the sticky silicone rubber from the wafer 10. Soft polymer layers exhibit inherently weak tensile strengths and, therefore, tend to crumble into particles quite readily. The hard surface film 50 protects the soft polymer layer and reduces the tendency for crumbling. Cleaning of soft polymer layers is normally difficult because of the tendency of particles and other contaminants to stick to the surface and to become embedded in the soft polymer material. This problem is also overcome by the presence of the hard surface film 50. In addition, the surface film 50 protects the soft polymer layer from damage by the ion beam when no wafer is present on the apparatus. Thus, the invention combines the benefits of soft elastomer cooling with the easy release, cleanliness and durability of harder substrates.

The thermal transfer apparatus 12 has been described thus far in connection with wafer cooling; that is, removal of thermal energy imparted to semiconductor wafer 10 by ion beam 20 or another energy source. It will be understood that the thermal transfer apparatus 12 can be utilized for wafer heating as well as for wafer cooling. Sputter coating is an example of a vacuum process where it is sometimes desirable to heat semiconductor wafers during processing. When heating is desired, the platen 34 is raised in temperature, and thermal energy is transferred through polymer layer 30 and surface film 50 to semiconductor wafer 10.

As noted hereinabove, the rate of thermal transfer from semiconductor wafers to prior art polymer layers has been limited. It has been found that this limitation is due in part to lack of contact between the wafer and the prior art polymer surface as shown in FIG. 3, which is greatly enlarged for ease of understanding. A prior art polymer layer 54 includes thermally-conductive particles 56. At least some of the particles 56 protrude above front surface 54a of polymer layer 54. As a result, when a wafer 58 is positioned on polymer layer 54, the protruding particles 56 prevent good contact with surface 54a and limit the rate of thermal transfer by conduction.

Prior art polymer layer 54 also includes voids or trapped gas bubbles 57, which reduce the thermal transfer rate and which can outgas during vacuum processing, and surface cavities 59 which reduce the area of contact between wafer 58 and front surface 54a and thereby also reduce the rate of thermal transfer.

It has been found that the protrusion of thermally-conductive particles above the surface of the polymer layer can be eliminated by fabricating the polymer layer in a mold in which careful attention is given to the mold surface that defines the upper, or wafer-contacting, surface of polymer layer 30. This mold surface is provided with a mold release material that is very smooth, preferably optically flat, and is sufficiently hard to prevent thermally-conductive particles from protruding above the wafer-contacting surface of polymer layer 30 during molding thereof. Prior art molding techniques utilized relatively soft mold-release materials such as grease, oil or wax. As shown in FIG. 4, which is greatly enlarged for ease of understanding, a polymer layer 60 includes thermally-conductive particles 62. Any particles 62 near surface 60a during the molding process are pressed into the bulk of the polymer layer 60 until curing is complete, thereby providing a smooth surface without protruding particles 62. As a result, a wafer 64 positioned on polymer layer 60 is in contact with surface 60a over virtually all of its back surface, and the rate of thermal transfer by conduction is greatly increased in comparison with prior art configurations. In FIG. 4, wafer 64 is shown slightly displaced above polymer layer 60 in order to illustrate that particles 62 do not protrude above the top surface of polymer layer 60. As described hereinafter, the mold release surface can be glass, hardened stainless steel, polyester film or any other material on which a smooth surface can be formed, which does not adhere to the polymer during molding and which is sufficiently hard to prevent protrusion of thermally-conductive particles during molding.

In the fabrication of silicone rubber layer 30, it is necessary to produce an extremely smooth surface which is free of protruding, thermally-conductive particles or other particles and which is free of surface cavities 59 caused by gas bubbles present during the molding process. Any such particles or cavities can reduce the rate of thermal transfer between the wafer and the silicone rubber layer. In addition, it is necessary that the bulk of the silicone rubber layer be free of trapped gas bubbles 57. Such trapped gas bubbles not only reduce the thermal transfer capability of the layer, but also outgas when the silicone rubber layer is placed in vacuum, thereby causing a virtual leak in the processing chamber. Therefore, the polymer layer 30 should be very pure and free of gas bubbles and other foreign matter.

Apparatus for molding the polymer layer 30 is illustrated in block diagram form in FIGS. 5A and 5B. A preferred mold structure is illustrated in FIG. 6. The apparatus of FIGS. 5A and 5B can be utilized to fabricate polymer layers 30 for one or more wafer sites. A mold 70 is utilized for forming the polymer layer 30 on aluminum platen 34. Molds 72 and 74 are utilized for forming additional polymer layers on additional platens (not shown) in a single molding process. The molds 70, 72, 74 are sealed vacuum-tight. A container 76 is sealed utilizing a cover 78 and an O ring 80. A tube 82 passes through an opening 84 in cover 78 and is connected to a mold cavity (not shown in FIG. 5A) in each of molds 70, 72, 74. The tube 82 is sealed to cover 78 by an O ring 86. Preferably, the tube 82 is flexible and is disposable after each molding process.

Within container 76 is a vessel 87 which contains a liquid resin 88 used to form the polymer layer 30. Typically, the resin 88 is formed as a mixture of two or more reacting components which are kept separate until the fabrication procedure begins. As used herein, the term "resin" is used to refer to the liquid form of the polymer layer prior to curing, in which form it can be pumped or injected into a mold. It will be understood that the resin 88 can be placed in the container 76 without using vessel 87. However, a separate vessel 87 provides the capability to keep the container 76 clean and to easily replace the resin 88 when desired.

The sealed container 76 is coupled by a conduit 90 through a valve 92 to a pressure source 94. The pressure source 94 can be an air pump or other means for pressurizing the container 76 to a desired pressure level of about 5 lbs/in². The container 76 is also coupled by conduit 90 through a valve 96 to a vacuum pump 98 which provides the capability to evacuate the sealed container 76 to a pressure level of about 1 torr.

The tube 82 is coupled vacuum-tight to one or more molds 70, 72, 74, and the end of tube 82 within container 76 is positioned outside the liquid resin 88. Valve 92 is closed and valve 96 is opened, causing vacuum pump 98 to evacuate both the sealed container 76 and the mold cavities in molds 70, 72, 74 as shown in FIG. 5A. The reduction in pressure in sealed container 76 promotes outgassing of gas bubbles in liquid resin 88, thereby providing a uniform and gas-free material.

Next, the end of tube 82 within container 76 is lowered below the surface of liquid resin 88 by sliding the tube 82 through O ring 86, valve 96 is closed and valve 92 is opened. Pressure source 94 provides the prescribed pressure within container 76, causing liquid resin 88 to be forced through tube 82 into still-evacuated mold cavities in molds 70, 72, 74 as shown in FIG. 5B. Since the mold cavities have been evacuated and the liquid resin 88 has been outgassed, the mold cavities are filled with liquid resin 88 which is substantially free of trapped gas bubbles. The resin 88 in the mold cavities is allowed to cure, either at room temperature or at an elevated temperature, to provide the polymer layer. The polymer layer formed by this process is highly uniform and free of surface cavities and trapped gas bubbles.

The details of one embodiment of the molds 70, 72, 74 are illustrated in FIG. 6. The aluminum platen 34, on which the silicone rubber layer is to be formed, is provided with a hole 102 between heat transfer surface 32 and the opposite surface. A flexible, resilient gasket 104 having an opening 106 is positioned on the heat transfer surface 32. The gasket 104 has a thickness equal to the desired thickness of the polymer layer, and the opening 106, typically circular, has a diameter equal to the desired diameter of the polymer layer. Preferably, the gasket 104 is formed of polyurethane. Then, an upper mold member 110, having a mold release surface 112, is placed over gasket 104 so as to form a sealed mold cavity 114 which defines the size and shape of the polymer layer to be molded.

As noted hereinabove, mold release surface 112 can be glass, hardened stainless steel, polyester film or another material having sufficient hardness to prevent thermally-conductive particles in resin 88 from protruding above the surface of the polymer layer, while avoiding adherence of the polymer layer thereto during curing. Preferably, the mold release surface 112 is made optically flat. When necessary, a mold release material in the form of an aerosol spray can be applied to mold release surface 112. A preferred aerosol spray is Teflon having particle sizes in the range of 1-5 micrometers. In one preferred embodiment, the mold release surface 112 can be a polyester film which transfers to polymer layer 30 during molding and which is retained on the polymer layer 30 after molding for protection during the remainder of the system assembly and test procedure. The polyester film is subsequently removed by peeling it from the polymer layer 30. The use of a resilient gasket 104 seals the mold cavity 114 and defines the thickness and the diameter of the polymer layer 30, while preventing flashing (leakage between the mold elements) and other irregularities at the peripheral edge of the polymer layer.

The tube 82 from sealed container 76 is coupled by a suitable vacuum-tight fitting (not shown) of conventional construction through hole 102 to mold cavity 114 for evacuation and subsequent filling of mold cavity 114 as described hereinabove. The resin in mold cavity 114 is allowed to cure, typically at room temperature. Subsequent to curing, the mold member 110 and gasket 104 are removed from platen 34, leaving soft polymer layer 30 adhered to the heat transfer surface 32.

Next, the platen 34 and the polymer layer 30 are placed in a plasma etcher such as a Drytek etcher commonly used to remove photoresist from wafers. The chamber of the etcher is evacuated, and oxygen is introduced into the chamber at a pressure level of about 400 microns. Radio frequency energy at a level of about one kilowatt is applied to the oxygen by the etcher so as to form an oxygen plasma in the chamber. While the platen 34 and the polymer layer 30 are not intentionally heated, the applied radio frequency energy raises their temperature to about 100° C. The platen 34 and the polymer layer 30 are left in the oxygen plasma for about 30 minutes, causing formation of the thin, relatively hard surface film 50 on polymer layer 30. The oxygen plasma treatment of the polymer layer 30 produces an extremely clean surface. In addition, the oxygen reacts with the silicon in the silicone rubber to form a silicon dioxide, or quartz, layer, preferably having thickness in the range of 0.1 to 5.0 micrometers. The thickness of the quartz layer depends on the oxygen plasma treatment time. Since silicone rubber consists of hydrogen, carbon and silicon, it is believed that the oxygen plasma erodes the hydrogen and carbon from the upper portion of the silicone rubber layer to form H₂ O and CO₂, leaving an upper layer of almost pure silicon. This silicon then reacts with the oxygen in the plasma to form the oxide layer. It is further believed that oils in the rubber bubble up during the oxygen plasma treatment and react with the oxygen to form silicon dioxide.

The above-described method for forming surface film 50 relies upon silicon contained within the silicone rubber layer for forming the oxide layer. It is believed that the reaction tends to be self-stopping, since the initially-formed surface film prevents or slows the reaction between the oxygen plasma and silicon from the underlying silicone rubber layer. In accordance with an alternate method for forming surface film 50, silicon from an independent source of silicon is provided at the surface of the silicone rubber layer to react with the oxygen plasma and form an oxide layer. An independent source of silicon for reaction with the oxygen plasma provides better control of the reaction, and self-stopping of the reaction is eliminated.

Silicon can be provided at the surface of the silicone rubber layer in any convenient manner. In one embodiment, an absorbent paper saturated with a volatile, silicon-containing compound is mounted above the silicone rubber surface. The silicon-containing compound can, for example, be silicone diffusion pump oil. In another embodiment, silane gas is introduced into the plasma etch chamber. In other embodiments, a silicon-containing material is sprayed onto the surface of the silicone rubber, or a solid silicon-containing material located in the plasma etch chamber is heated to produce a vapor at the surface of the silicone rubber layer. All that is necessary is to provide silicon at the silicone rubber surface in an amount sufficient to support a reaction with the oxygen plasma.

By providing an independent source of silicon, the surface film can be formed at a lower temperature than is required when silicon is derived from the silicone rubber layer itself. In an example of the present method, a paper saturated with silicone diffusion pump oil was positioned in the plasma etch chamber about 0.25-inch to 1.5-inches above the surface of the silicone rubber layer. An oxide surface film was formed at temperatures approximately 30°-40° C. lower than results obtained without an independent source of silicon.

In some cases, it may be desirable to heat the silicone rubber layer prior to oxygen plasma treatment in order to drive off volatile silicon-containing materials. When this is done, the surface film is formed almost entirely from the independent silicon source, and better control of the reaction is obtained.

A block diagram of apparatus suitable for formation of the thin surface film is illustrated in FIG. 8. Platen 34, having thermally-conductive layer 30 thereon, is positioned in a plasma etch chamber 140. As noted above, the plasma etcher can be a conventional Drytek etcher, such as a Model MS-5. The plasma etcher includes RF electrodes 142, coupled to an RF energy source (not shown). The plasma etch chamber 140 is coupled to a vacuum pump 144 and to an oxygen source 146. An independent silicon source 150 is located in chamber 140 near the surface of thermally-conductive layer 30.

In operation, the vacuum pump 144 evacuates chamber 140, and oxygen is introduced from source 146 at a controlled pressure of approximately 400 microns. The RF electrodes 142 are energized, causing formation of an oxygen plasma. The oxygen plasma reacts with silicon from silicon source 150 to form a thin, hard oxide film on the surface of thermally-conductive layer 30. The reaction is allowed to continue until the surface film has a thickness in the range of 0.1-5.0 micrometers. Then the chamber 140 is vented, and the platen 34 is removed.

It has been found that the oxide (quartz) surface film 50 is easily fractured into multiple plates varying in dimension from about 5 to 1,000 micrometers across. The plates can be created by applying a mechanical stress, a thermal stress or a combination thereof to the film 50. The quartz plates do not flake off the silicone rubber surface since they are formed as an integral part of it. Since each of the multiple plates moves independently, they conform to surface irregularities on the back of the wafer and to particles inadvertently trapped between the wafer and the polymer layer. As a result, cooling performance is substantially enhanced.

The method for fabricating the polymer layer 30 is summarized in FIG. 7. Initially, gasket 104 and mold member 110 are attached to platen 34 to form mold cavity 114, as indicated in step 120, and resin 88 in vessel 87 is placed in container 76 and cover 78 is sealed thereto. Next valve 96 is opened, and mold cavity 114 and container 76 are evacuated in step 122. Tube 82 is immersed in resin 88, valve 96 is closed and valve 92 is opened so that pressure source 94 pumps resin into mold cavity 114, as indicated in step 124. The resin is permitted to cure in step 126, and gasket 104 and mold member 110 are removed in step 128. Finally, the platen 34 and polymer layer 30 adhered thereto are subjected to oxygen plasma treatment to form surface film 50 in step 130.

It will be understood that other techniques for forming the surface film 50 are included within the scope of the present invention. For example, deposition of silane gas and oxygen on the silicone rubber surface can be utilized to form the oxide layer. In addition, the surface film can be formed of another smooth, plate-like material such as graphite. Graphite, mechanically deposited and rubbed so as to adhere to the surface of a silicone rubber layer, produces enhanced thermal transfer and does not adhere to wafers. The primary requirement is to provide a thin, smooth and relatively hard surface film on a relatively soft, thermally-conductive polymer layer. The surface film prevents sticking and permits intimate contact with the semiconductor wafer. The soft polymer layer and its surface film both conform to the back surface of the wafer and both have high thermal conductivity so that overall thermal transfer performance is greatly improved. Thermal contact resistances have been measured with the thermal transfer apparatus disclosed herein at about 10° C./watt/cm². By contrast, a good performance with gas cooling is about 40° C./watt/cm² and typical performance with prior art polymer layers is about 50°-60° C./watt/cm².

While there have been shown and described what are at present considered the preferred embodiments of the present invention, it will be obvious to those skilled in the art that various changes and modifications may be made therein without departing from the scope of the invention as defined by the appended claims. 

What is claimed is:
 1. A method for treating a thermally-conductive polymer layer used for thermal transfer with a workpiece to prevent adherence of the workpiece to a surface of the polymer layer, comprising the steps of:treating said polymer layer with oxygen plasma; and providing silicon at the surface of said polymer layer during oxygen plasma treatment to cause formation of a thin surface film on said polymer layer, said surface film being harder than said polymer layer.
 2. A treatment method as defined in claim 1 wherein the step of treating said polymer layer with oxygen plasma includes placing said polymer layer in a plasma chamber and wherein the step of providing silicon includes providing an independent source of silicon in said plasma chamber.
 3. A treatment method as defined in claim 2 wherein the step of providing a source of silicon includes providing a volatile silicon-containing material on an absorbent member located in said plasma chamber.
 4. A treatment method as defined in claim 2 wherein the step of providing a source of silicon includes introducing a gaseous silicon-containing material into said plasma chamber.
 5. A treatment method as defined in claim 2 wherein the step of providing a source of silicon includes spraying a silicon-containing material onto the surface of said polymer layer.
 6. A treatment method as defined claim 1 further including the step of heating said polymer layer prior to the step of treating said polymer layer with oxygen plasma in order to drive volatile materials from said polymer layer.
 7. A treatment method as defined in claim 1 wherein the steps of treating said polymer layer with oxygen plasma and providing silicon at the surface of said polymer layer are continued until said surface film has a thickness in the range of 0.1 to 5.0 micrometers.
 8. A method for treating a thermally-conductive silicone rubber layer used for thermal transfer with a semiconductor wafer to prevent adherence of the wafer to a surface of the silicone rubber layer, comprising the steps of:treating said silicone rubber layer with oxygen plasma in a plasma chamber; and providing silicon from an independent source at the surface of said silicone rubber layer during oxygen plasma treatment to cause formation of a thin surface film on said silicone rubber layer, said surface film being harder than said silicone rubber layer.
 9. A treatment method as defined in claim 8 wherein the step of providing silicon includes providing a volatile silicon-containing material on an absorbent member located in said plasma chamber.
 10. A treatment method as defined in claim 8 wherein the step of providing silicon includes introducing a gaseous silicon-containing material into said plasma chamber.
 11. A treatment method as defined in claim 8 wherein the step of providing silicon includes spraying a silicon-containing material onto the surface of said silicone rubber layer
 12. A treatment method as defined in claim 8 further including the step of heating said silicone rubber layer prior to the step of treating said silicone rubber layer with oxygen plasma in order to drive volatile materials from said silicone rubber layer.
 13. A treatment method as defined in claim 8 wherein the steps of treating said silicone rubber layer with oxygen plasma and providing silicon at the surface of said silicone rubber layer ar continued until said surface film has a thickness in the range of 0.1 to 5.0 micrometers.
 14. A treatment method as defined in claim 8 wherein said surface film comprises silicon dioxide.
 15. A method for treating a thermally-conductive polymer layer used for thermal transfer with a workpiece to prevent adherence of the workpiece to a surface of the polymer layer, comprising the steps of:providing oxygen and silicon at the surface of said polymer layer; and elevating the temperature at the surface of said polymer layer sufficiently to cause reaction of said oxygen and silicon to form a surface film on said polymer layer that is harder than said polymer layer.
 16. A method for effecting thermal transfer with a workpiece in vacuum, comprising the steps of:providing a thermally-conductive platen including a heat transfer surface having a soft, thermally-conductive polymer layer affixed thereto; forming on said polymer layer a thin surface film for contacting said workpiece without adhering thereto by treating said polymer layer with oxygen plasma and providing silicon from an independent silicon source at the surface of said polymer layer during oxygen plasma treatment; and placing the workpiece in contact with the surface film.
 17. A method as defined in claim 16 wherein the step of forming a thin surface film is continued until said surface film has a thickness in the range of 0.1 to 5.0 micrometers. 